Study of electric - field - induced phase transitions in [ 111 ] oriented 0 . 955 Pb ( Zn 1 / 3 Nb 2 / 3 ) O 3 – 0 . 045 PbTiO 3 single crystals

نویسندگان

  • Mingrong Shen
  • Donglai Yao
  • Wenwu Cao
چکیده

We report the presence of a field-induced intermediate ferroelectric phase in pre-poled [111] oriented 0.955Pb(Zn1 / 3Nb2 / 3)O3– 0.045PbTiO3 (PZN–4.5%PT) single crystals, based on the dielectric, differential scanning calorimetry and pyroelectric measurements. It was found that this phase exists in a very narrow interval of 4.3 -C between the ferroelectric rhombohedral and tetragonal phases. This may be explained as an electric-field-induced orthorhombic phase based on previous investigations on the PZN–8%PT single crystals. An electricfield-induced phase diagram of <111> oriented PZN–PT has been redrawn based on this study. D 2005 Elsevier B.V. All rights reserved. PACS: 77.22.-d; 77.84.Dy; 64.70.-p

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تاریخ انتشار 2005